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Interesting facts about plastics and rubber

We come across plastics and rubber everywhere in our daily lives. Discover fascinating stories, surprising facts and interesting background information – from historical developments and well-known products to key figures and innovations in the industry.

Results (423)

  • Babies’ lives saved thanks to polymer material from 3D printers

    The innovative applications for which 3D printers are being used is demonstrated most impressively by taking a look at specific individual cases. In the USA, customised implants have been manufactured for the first time by the 3D printing process from biodegradable polymer materials, with which the lives of young children can be saved who have suffered from severe respiratory problems ever since they were born. Statistically speaking, one in every 2,200 children is born suffering from tracheomalacia [1]; this condition is characterised by flaccidity of the tracheal support cartilage. Due to tissue weakness, there is a danger of the trachea collapsing during both the inspiration and expiration phases due to the vacuum that forms in the organ. The consequence is that breathing resistance increases; the patient can suffocate. This fate was shared by Kaiba Gionfriddo, who was not quite two years old, and Garrett Peterson, who was only a few weeks old [2, 3]. The Kaiba Gionfriddo case Glenn Green, associate professor of pediatric otolaryngology at the University of Michigan, decided to adopt an approach that had not been tried before in order to make sure that his patient Kaiba survived. His thinking was to stabilise the child’s unstable bronchus by integrating tubular splints in the course of an operation so that Kaiba stayed alive. Green was assisted in development of his idea and creation of an implant by his colleague Scott Hollister, professor of biomedical engineering and mechanical engineering and associate professor of surgery at the University of Michigan. The material chosen to produce the implant was polycaprolactone, an oil-based thermoplastic, which has properties that make it particularly suitable for medical applications. Let us take a look at some of the properties of this polycaprolactone material. Properties of polycaprolactone material Polycaprolactone consists of a series of methylene units, between which ester groups are formed. The very simple structure of the polymer makes it possible to rotate the individual links in the chain on an almost unlimited basis; the glass transition temperature (Tg), i.e. the curing temperature, is very low. At room temperature, short-chain, amorphous (molecularly random) polycaprolactone is soft and rubbery. Due to the consistent structure, it crystallises well, however – which describes the opposite of the amorphous state; the material is reinforced as a result. [4] Polycaprolactone is biologically degradable too. It is degraded by microorganisms, generally in the absence of oxygen (anaerobic). It is likely that this highly significant fact is what made it extremely interesting to Green and Hollister. The material blends well too; it combines with other plastics as well as with lignin [5], gels, starch and other materials. It also sticks to many different surfaces, is easy to process, melts well and is not toxic, which is particularly important if the material is supposed to be used in the human organism. The foundations had been laid, so that Green and Hollister started practical implementation once the US “Food and Drug Administration” (FDA) approved the project and thus gave them the go-ahead. 3D printing chosen as the manufacturing process On the basis of a model of the bronchi, which was developed with the help of imaging techniques, a process had to be found that enabled tubular splints a few centimetres long to be manufactured from polycaprolactone quickly, efficiently and precisely enough. 3D printing proved to be particularly suitable in every respect – for the production of a scale model of the bronchi too. 3D printing is a manufacturing process that involves primary shaping, i.e. the production of a solid body from a shapeless material, as is the case in casting, sintering or extrusion too, for example. Three-dimensional workpieces with specified dimensions and shapes are produced in a 3D printer from one or more liquid or solid materials with the help of computers (CAD) [6]. What were in the final analysis produced by this process were stent-like rings one to two centimetres long with partial longitudinal openings that were placed over the collapsing bronchi and were sewn around them in an operation. The splints enclosed the bronchi like an external framework or skeleton, allowing Kaiba to breathe freely and enabling the respiratory tract to grow properly. “It was amazing”, Glenn Green remembers. “As soon as the splint was put in, the lungs started going up and down for the first time and we knew he was going to be OK.” And Scott Hollister adds with reference to the material used: “It takes about two to three years for the trachea to remodel and grow into a healthy state, and that’s about how long the polycaprolactone will take to dissolve into the body.” What is a help for one child cannot be bad for another one: the Garrett Peterson case Information about the successful treatment of 20-month-old Kaiba Gionfriddo spread and reached the parents of Garrett Peterson – who was only a few weeks old – too. This child has also been suffering from the effects of tracheomalacia from birth and his parents feared that their son would probably never be able to live without a ventilator. Then they heard the news about Kaiba ... Hollister created a 3D model of Garrett’s airway and custom splints made from polycaprolactone. Garrett’s chest was finally opened on 31. January 2014 for what his parents hoped would be a successful operation by Richard G. Ohye, head of pediatric cardiovascular surgery at the University of Michigan. What he saw initially was anything but encouraging, however. The boy’s windpipe had already collapsed and one of his lungs was completely white – like in a dead person. Ohye sewed a splint around Garrett’s right and left bronchi. Following the procedure, the mood turned tense. Everyone was relieved when air flowed into the lungs and the windpipe stayed open without collapsing. The long wait had come to an end. In the coming three years, during which the polycaprolactone splints slowly dissolve into Garrett’s little body, he would get enough air. His organs will be able to grow and develop just like a healthy child. Thanks to smart minds, modern medicine, ingenious technology and, last but not least, innovative polymer materials. Guido Deußing Quelle [1] de.wikipedia.org/wiki/Tracheomalazie [2] www.plasticstoday.com/articles/3d-printed-plastic-saves-babys-life0524201301 [3] www.plasticstoday.com/articles/how-3d-printing-saving-lives-again [4] de.wikipedia.org/wiki/Polycaprolacton [5] www.freidok.uni-freiburg.de/volltexte/257/ [6] de.wikipedia.org/wiki/3D-Drucker

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  • Polymer researchers can more than plastic

    The UV-absorber (here as the logo of Kiel University’s Faculty of Engineering) is even applicable on flexible materials. [Foto: D. Schimmelpfennig/CAU] Ultraviolet light (UV) has not only harmful effects on molecules and biological tissue like human skin but it also can impair the performance of organic solar cells upon long-term exposure. Researchers of Kiel University and Helmholtz-Zentrum Geesthacht have now developed a so-called plasmonic metamaterial, which is compatible with solar technology and completely absorbs UV light – despite being only 20 nanometers thin. It is one of the first metamaterial perfect absorbers designed for such high frequency. The study was recently published in the renowned scientific magazine “Applied Physics Letters”. "Metamaterials are artificial materials composed of designed unit cells which can show striking and unique electromagnetic properties not inherent in the individual constituent components. These artificially structured composites could potentially fill the gap in the electromagnetic spectrum where material response is limited and facilitate the building of new devices", explains Mehdi Keshavarz Hedayati, member of the group Nanochemistry and Nanoengineering at Kiel University and first author of the paper. In organic solar cells, degradation of the cells by long exposure to sunlight (i.e. UV exposure) is a challenging problem, which limits the application of organic cells. Therefore, a material that totally blocks the UV light could principally improve the durability of this class of solar collecting materials. "Since our perfect absorber can be deposited on even flexible substrates, we envision that this structure can be potentially used also in thin film solar panels which are intended to be used in next generation clothing industry", Hedayati adds. The researchers’ metamaterial stays highly absorbent even at oblique light incidence which is very advantageous for their potential application for solar energy. "We have had already shown the high absorption of this class of metamaterials in our previous articles but here, we shifted the operation frequency of our former perfect absorber to a higher frequency (UV) by replacing gold or copper by silver", Professor Mady Elbahri says, head of a joint research group of Helmholtz-Zentrum Geesthacht and Kiel University and leader of the project. "The fabrication of any metamaterial to operate in UV frequency is a very hard task with the existing nanolithography based methods. Our designed metamaterials are fabricated with co-sputtering which is a routine technique in thin film technology and that makes our idea applicable for large scaling." "The current approach is enjoying ease of fabrication and its large scaling is relatively cheaper compared to other metamaterials fabrication methods." say Professor Franz Faupel and Dr. Thomas Strunskus from Kiel University’s Multicomponent Materials research group, coauthors of the study. “We still have to work, though, to improve the system’s performance and stability in harsh environments”. Nevertheless, it is conceivable that the new concept will find application in many other fields than solar technology as well. In medicine, for instance, where it could be used in sensors to detect cancer pathogens in the human body. The idea brought Professor Mady Elbahri the special prize of the Schleswig-Holstein "ideas competition" in 2012. The work on the absorber also brought Mehdi Hedayati the "Khwarizmi Youth Award", a prize given to young Iranian researchers by the Iranian Ministry of Education for outstanding achievements. Elbahri and his colleagues are members of the Collaborative Research Center 677 “Function by Switching”, which is funded by the German Research Foundation (DFG). Here, the scientists investigate molecules, which work like machines and could make Elbahri’s absorber smart. Instead of metal particles in the top layer, they want to use molecules, which can be switched on and off and thus control the device’s function. Information about the new material: The researchers designed a structure that is composed of three main layers. The top layer, which is exposed to the light, is a nanocomposite wherein nanoparticles of silver, with an average diameter of 5 nanometers, are dispersed in a silicon dioxide matrix. A silicon dioxide film and a silver film constitute the second and third layer. In this stack, the whole UV-A light gets absorbed due to the intelligent structural design: the silver film (bottom layer), functioning as a mirror, multiplicatively reflects the incident light which interacts with the silver nanoparticles and gets absorbed or scattered. Additionally, light destructively interferes between the layers and hence reduces the reflectance. A strong light confinement between the small gaps of the particles due to collective oscillations of the conduction electrons of the nanoparticles, so-called surface plasmons, adds it all up to a perfect absorbing material. Source: Plasmonic tunable metamaterial absorber as ultraviolet protection film. M. K. Hedayati, A. U. Zillohu, T. Strunskus, F. Faupel and M. Elbahri, Appl. Phys. Lett. 104 , 041103 (2014) Further information: Helmholtz-Zentrum Geesthacht - Zentrum für Material- und Küstenforschung

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  • Put a plastic bag in your tank

    Plastic waste into liquid fuel as a way to re-use discarded plastic bags and other products. (Source: istockphoto) Researchers in India have developed a relatively low-temperature process to convert certain kinds of plastic waste into liquid fuel as a way to re-use discarded plastic bags and other products. They report full details next month in the International Journal of Environment and Waste Management. Many pundits describe the present time as the "plastic age" for good reason and as such we generate a lot plastic waste. Among that waste is the common polymer, low-density polyethylene (LDPE), which is used to make many types of container, medical and laboratory equipment, computer components and, of course, plastic bags. Recycling initiatives are in place in many parts of the world, but much of the polyethylene waste ends up in landfill, dispersed in the environment or in the sea. Chemist Achyut Kumar Panda of Centurion University of Technology and Management Odisha, India is working with chemical engineer Raghubansh Kumar Singh of the National Institute of Technology, Orissa, India, to develop a commercially viable technology for efficiently rendering LDPE into a liquid fuel. Given that most plastics are made from petrochemicals, this solution to plastic recycling brings the life-cycle full circle allowing a second use as an oil substitute. The process could, if implemented on a large enough scale, reduce pressures on landfill as well as ameliorating the effects of dwindling oil supplies in a world with increasing demands on petrochemicals for fuel. In their approach, the team heats the plastic waste to between 400 and 500 Celsius over a kaolin catalyst. This causes the plastic's long chain polymer chains to break apart in a process known as thermo-catalytic degradation. This releases large quantities of much smaller, carbon-rich molecules. The team used the analytical technique of gas chromatography coupled mass spectrometry to characterize these product molecules and found the components of their liquid fuel to be mainly paraffins and olefins 10 to 16 carbon atoms long. This, they explain, makes the liquid fuel very similar chemically to conventional petrochemical fuels. In terms of the catalyst, Kaolin is a clay mineral - containing aluminum and silicon. It acts as a catalyst by providing a large reactive surface on which the polymer molecules can sit and so be exposed to high temperature inside the batch reactor, which breaks them apart. The team optimized the reaction at 450 Celsius a temperature with the lowest amount of kaolin at which more than 70% of the liquid fuel is produced. In other words, for every kilogram of waste plastic they could produce 700 grams of liquid fuel. The byproducts were combustible gases and wax. They could boost the yield to almost 80% and minimize reaction times, but this required a lot more catalyst 1 kg of kaolin for every 2 kg of plastic. GDeußing Source:"Thermo-catalytic degradation of low density polyethylene to liquid fuel over kaolin catalyst" in Int. J. Environment and Waste Management, 2014, 13, 104-114

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  • Ocean and polymers: time to accept responsibility

    The oceans are the biggest and as yet least explored biosphere on the earth. We have, however, succeeded in increasing our understanding of the marine ecosystem to a substantial extent in recent decades – and have been forced in this context to face the fact that we have made things excessively tough for the sea. The consequences of our actions are obvious. Callum Roberts, marine biologist and Professor of Marine Conservation at the University of York in England, puts it in a nutshell when he points out that the oceans have been overfished and are full of garbage and toxic substances [1]. The harmful effects of what we do are evident not just close to the surface but also deep below it. It is essential that something is done about this. Die-hard pessimists seem to think that it is pointless to fight for marine protection, however, in view of what they feel are the almost superhuman efforts that are needed to reverse the trend and in view of the enormous resources available to various interest groups that are primarily interested in economic exploitation of the marine ecosystem – in spite of the probable negative impact of this, about which environmental organisations issue constant warnings. Let us focus solely on the status quo, maintenance of which can already be considered a challenge. The ingredients on which the success of this depends are: immediate rethinking, considerable discipline and a tremendous amount of energy. We are told that it is time to accept responsibility – at the international level. This appeal is directed at global society, at all people, irrespective of their political views, cultural background or religious beliefs, at governments, the business community and industry. The feeling of powerlessness in the face of the size of the task has to be overcome, so that action is at long last taken. What is necessary here is a “Kaizen” process, i.e. changing (“Kai”) for the better (“Zen”). More exactly: everything is at stake! What is needed in the long term is therefore more than just goodwill. Today and in future, it is lateral thinkers, inventors and visionaries that are essential, who have imaginative ideas for effective innovations in such areas as energy generation and storage, raw material and food supply, waste prevention and recycling as well as use of air, land and water in a way that is both environmentally sound and economically viable. If they are taken decisively in the right direction, even small steps can lead to changes for the better. The "Blue Planet": The earth is covered with water to approximately 70 percent. (Source: NASA) Life depends on clean water Human beings need an intact environment to exist. It is essential and irreplaceable. Protecting and maintaining the earth in all its diversity also means drawing attention to the water that is vital to life and thus to the world’s oceans, the cradle of life, the reason why our “blue planet” is unique in the universe. It is up to us to avoid damage and to make sure that not only we human beings but also the flora and fauna survive. Although this is not an easy task, the problems will only become even more difficult to solve if we fail to tackle them resolutely now and hesitate to start taking sensible action that has long-term impact. All of us can probably remember watching a plastic bag blowing across the road. This scene alone says a great deal about how we see things as well as about the special features of polymer materials: they are lightweight but stable at the same time, they can be given individual designs and are versatile in their applications. Our world would not be the way it is without polymers. What is, however, often forgotten is that most plastics are extremely valuable energy sources, while they survive for hundreds of years – which is both a blessing and a curse. Those who are opposed to plastic use the word disparagingly, while plastic is a positive term to its supporters; while some chemists are fascinated by the polymer structure, others are interested in the petrochemical raw material from which plastics are primarily manufactured, well aware of the fact that their high energy content is a significant factor in electricity and heat generation. It is rarely the case, however, that plastics and polymers are recognised for what they really are: valuable materials that influence and enrich all aspects of our lives considerably. Thopuc of the Month: Plastics move the world Even though deposit systems in Germany and elsewhere have improved the image of polymer bottles, raising them to the same level as glass bottles and enabling them to be recycled in the same way, we are still far from reaching an ideal state in the way we handle plastics: most people would find it a strange idea to bend down and pick up a plastic bag in the way one would do so to pick up a coin. Literally “bowing down” before the polymer material like this would, however, be an effective way to initiate a global healing process in one small area. Plastic residue have collected in at least five places around the world’s oceans. (Source: U.S. National Oceanic and Atmospheric Administration) Plastics reach the world’s oceans primarily via waterways. It has not yet been determined conclusively what ultimately happens to them in the sea. No final answers have been found so far to many questions about, for example, the maritime transport channels and mechanisms; there are at best assumptions and initial investigations. In spite of this, what is certain is that the beaches of remote islands in isolated locations like Easter Island in the southeastern Pacific have also been affected by the synthetic waste our civilisation produces and are littered with our plastic debris. Experts do in addition agree that not inconsiderable amounts of plastic residue have collected in at least five places around the world’s oceans due to current flows and form areas that rotate around their own axis on a continental scale. At some time or other, plastic disintegrates into tiny fragments known as microplastic under the influence of salt, water and the sun. This microplastic does not, however, degrade to any further extent than this and certainly does not dissolve completely as is observed with organic material like wood. Microplastic spreads around the ocean; it ends up on beaches, where it mixes with the sand; it floats with plankton in the surface water of the sea, where its size, shape and colour mean that fish, mammals living in the ocean and seabirds confuse it with food and eat it. A varying number of plastic fragments is frequently found in dead seabirds; if a maximum of ten is counted, then the water is considered to be clean ... It is not known whether microplastic caused the animals’ death; it is difficult to settle this question at the experimental level. The background information behind the investigations made does, however, indicate a dangerously dynamic development that should give us all food for thought: one of the characteristics of plastic is that it removes – extracts, the experts say – and accumulate pesticides, heavy metals and other environmental poisons from water. Animals that eat microplastic ingest these toxins as well, so that they accumulate in their tissue. At the end of the food chain, the animals end up as seafood on our plates. It is only a question of time until unforeseen developments climb the evolutionary ladder and reach us. Marine pollution cannot be attributed solely to microplastic that is due to the disintegration of plastic residue. Some pollution is the direct result of waste water flows. Studies completed in Japan, for example, have revealed that plastic pellets which are an important additive in the raw materials used in plastic processing or in consumer and/or personal products (e.g. toothpaste) contribute to marine pollution too. Although the sources of contamination may well be different, the impact on the marine environment and the creatures that live in it remains fundamentally the same. The inhabitants of Easter Island cleared their entire island of trees in order to build statues for their gods and then died of starvation when the soil dried out. (Source: istockphoto) Don’t look the other way It can be concluded from what has been outlined so far that the prospects for our environment and thus for us as its inhabitants may not be encouraging, but they are not hopeless. It would be completely wrong simply to look the other way and to let things run their course in an – ultimately irresponsible! – fatalistic belief that a catastrophe is inevitable. The opposite is the case: appropriate, intelligent action needs to be taken now. The marine biologist Callum Roberts reports that there are enough examples in history which demonstrate how civilisations were destroyed by environmental catastrophes that they unknowingly brought on themselves: “The inhabitants of Easter Island cleared their entire island of trees in order to build statues for their gods and then died of starvation when the soil dried out. The people of Mesopotamia developed an agricultural system with ingenious irrigation procedures, but in the end this method meant that the fields contained so much salt that no crops grew on them any more. The process adopted by the Maya to farm mountain slopes involved the removal of all the topsoil in the entire region, so that a long drought led to the collapse of this unusual culture.” [1, P. 14] In just five years, predicted Boyan Slat, could be estimated fishing around seven million tons of plastic out of the sea. (Source: Boyan Slat) We are not blind; we can see perfectly clearly. Even if we have the impression that we are shutting the stable door after the horse has bolted, this is not the case by a long way. A longing for change has always proved to be a strong driving force throughout the history of humankind. Some research scientists are convinced that at least the plastic in the world’s oceans could be removed in only a short time. One of these idealists is the 20-year-old Dutchman Boyan Slat. This aerospace engineering student has ideas, visions and a sense of mission. He predicts that an estimated roughly seven million tonnes of plastic debris – the equivalent of the weight of 1,000 Eiffel Towers – could be fished out of the sea in only five years. How is this supposed to be possible? According to the budding engineer, with the help of enormous filteringsystems anchored to the ocean floor and floating on the surface of the water, that catch all plastics via arms attached to their sides and fish them out of the water. The system operates passively, using only ocean currents, which wash the plastic particles in the direction of the filtering platform, where they are extracted and collected. Plankton that is important for the creatures living in the ocean would be washed out, while the plastic could be recycled in a profitable business operation (including rare earths, the natural reserves of which have been exhausted almost completely and which supposedly adhere in large quantities to the plastics afloat in the sea. Would it be possible to put Boyan Slat’s idea into practice? Some people may well consider the young, up-and-coming scientist to be naive. But isn’t that what we need at the present time, people who are willing to think outside the box and to fight for what appear to be crazy ideas too? One can only hope so: according to an estimate compiled by the United Nations, about 6.5 million tonnes of new debris reach the oceans every year. Das "Ocean- clean-up"-Projekt von Boyan Slat. Tray Mincer and colleagues found cells that chew floating micro-plastic in the sea. (Source: Woods Hole Oceanographic Institution in Woods Hole, Massachusetts/USA) Mother Nature finds a way While just a few people are racking their brains to try and find a way to reduce marine pollution by microplastic, Mother Nature has evidently developed a concept of her own to deal with the problem. Tracy Mincer from the Woods Hole Oceanographic Institution in Woods Hole, Massachusetts/USA, came to this conclusion recently. The marine biologist and his team of scientists discovered in electromicroscopic examinations of plastic debris from the Sargasso Sea, part of the Atlantic Ocean east of Florida, that bacteria-like cells settle in small notches on the surface of plastics. Tracy Mincer and his colleagues report that it seems as if the cells they monitored in the “plastisphere” were literally eating away the plastic [2]. Microbes that digested plastics had apparently already been found on landfill sites; now they had for the first time discovered bacteria in the sea that evidently have similar capabilities. Tracy Mincer and his colleagues are still only in the initial stages of their investigation at the present time, although a decision has been taken to continue it. The objective is to grow cultures of the cells that devoured plastic residue in the ocean – without harming the marine environment. If Mincer’s research approach proves to be correct and the results are promising, this would be major progress towards clean oceans. We should not rely on this being the case, however. It might perhaps even be sensible to assume the opposite. Then there would be a good chance of initiating a process of rethinking, at the end of which we at long last see plastics as being more significant and valuable – so that we then no longer throw them away unthinkingly in the environment. Because this is the main problem. Guido Deußing Literatur: [1] Callum Roberts: Der Mensch und das Meer. Warum der größte Lebensraum der Erde in Gefahr ist. Munich: Deutsche Verlags-Anstalt 2013 [2] Erik R. Zettler, Tracy J. Mincer, Linda Amaral-Zettler: Life in the “Plastisphere”: Microbial Communities on Plastic Marine Debris. Environ. Sci. Technol., 2013, 47 (13), pp. 7137-7146 Further information: Greater sustainability and protction of freshwater lakes (01/2013) Plastics bags on trial (TdM 10/2011)

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  • First plastic cell with working organelle

    A close-up of a polymer cell with organelles. (Source: Radboud University Nijmegen) For the first time, chemists have successfully produced an artificial cell containing organelles capable of carrying out the various steps of a chemical reaction. This was done at the Institute for Molecules and Materials (IMM) at Radboud University Nijmegen. The discovery was published in the first 2014 issue of the journal Angewandte Chemie. [1] It is difficult for chemists to match the chemistry in living cells in their laboratories. After all, in cells all kinds of complex reactions are taking place simultaneously in a small area, in various compartments and incredibly efficiently. This is why chemists attempt to imitate the cell in various ways. In doing so, they also hope to learn more about the origin of life and the transition from chemistry to biology. A research team led by Jan van Hest (Radboud University) and Sébastien Lecommandoux (University of Bordeaux) created their organelles by filling tiny spheres with chemicals and placing these inside a water droplet. They then cleverly covered the water droplet with a polymer layer – the cell wall. Using fluorescence, they were able to show that the planned cascade of reactions did in fact take place. This means that they are the first chemists to create a polymer cell with working organelles. 'Just like in the cells in our bodies, the chemicals are able to enter the cell plasma following the reaction in the organelles, to be processed elsewhere in the cell,' Ruud Peters, PhD candidate on the project, explains. Search for the origin of life Creating cell-like structures is currently very popular in the field of chemistry, with various methods being tried at the Institute for Molecules and Materials (IMM). Professor Wilhelm Huck, for example, is making cells from tiny droplets of solutions very similar to cytoplasm, and Van Hest’s group is building cells using polymers. ‘Competing groups are working closer to biology; making cells from fatty acids, for example. We would like to do the same in the future. Another step would be to make cells that produce their own energy supply. We are also working on ways of controlling the movement of chemicals within the cell, towards organelles. By simulating these things, we are able to better understand living cells. One day we will even be able to make something that looks very much like the real thing...’ GDeußing [1] Ruud J. R. W. Peters1, Maïté Marguet, Sébastien Marais, Marco W. Fraaije, Jan C. M. van Hest, Sébastien Lecommandoux, Cascade Reactions in Multicompartmentalized Polymersomes Angewandte Chemie – International Edition, Volume 53, issue 1, pg. 146-150, January 2014

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  • Polymer Coatings Based on Molecular Structures

    A novel method developed by researchers from Karlsruhe Institute of Technology (KIT) and Jacobs University Bremen enables manufacturing of polymer layers with tailor-made properties and multiple functions: A stable porous gel (SURGEL) for biological and medical applications is obtained from a metal-organic framework (SURMOF) grown up on a substrate. The method is presented in the renowned Journal of the American Chemical Society. Coating of solids with polymers plays a central role in many areas of technological, natural and life sciences. For example, implants for the human body e.g., cardiac pacemakers, stents, or joint prostheses, need to be coated with suitable biomaterials and then impregnated with medical agents to accelerate healing-in and suppress inflammations. KIT researchers now have developed a completely novel method for producing a gel from cross-linked organic components. “Compared to conventional polymer coatings, this gel stands out by the fact that the pore size of the layers can be specifically adapted to the bioactive substances e.g., to pharmaceutical agents, to be embedded,” explains Professor Christof Wöll, Head of KIT’s Institute of Functional Interfaces (IFG). Figure: Schematic diagram of a metal-organic framework (SURMOF, left), the framework after cross-linking (center), and after copper ions have dissolved out (right). (Graphic: Dr. Manuel Tsotsalas/IFG). The gel fabrication method developed by researchers from the KIT Institute of Functional Interfaces (IFG), Institute for Biological Interfaces (ITG), and Institute for Organic Chemistry (IOC) together with the Jacobs University Bremen consists of several steps: First, a layer of a so-called metal-organic framework (MOF) is grown up on a solid substrate. In the obtained SURMOF (SURface-mounted Metal Organic Framework) layer, the size, shape, and chemical functionality of the pores can be tailored, so to speak. The layer itself, however, is not suited for use in biological environments: Its pronounced sensitivity to water causes it to be degraded very rapidly and the copper ions contained in that special type of SURMOF are toxic to living beings. In view of the above, the molecular components in the SURMOF are cross-linked with another molecule in a second step using the particularly efficient so-called click chemistry method which already at room temperature allows a complete reaction. In a third step, one dissolves out the copper ions from the framework until obtaining the remaining cross-linked organic components that form a porous polymer. This SURGEL provides a uniformly thick layer and combines the advantages of the SURMOF with a high stability under biological conditions. The potential for biological and medical applications was demonstrated by the researchers by impregnating the SURGEL with a bioactive molecule and then populating it with microbes. The behavior of these simple cells showed that the released messenger molecules were incorporated extremely efficiently. “This new material class opens up entirely new possibilities of influencing cellular growth,” says Professor Martin Bastmeyer from KIT’s Zoological Institute who together with Professor Wöll heads the program “BioGrenzflächen” (bioInterfaces) supported by the Helmholtz Association. Both implementation of the novel polymer coating and its subsequent biological characterization have been demanding interdisciplinary cooperation of researchers in organic chemistry, biology, and physical chemistry from KIT and theorists from Jacobs University Bremen. Source: Manuel Tsotsalas, Jinxuan Liu, Beatrix Tettmann, Sylvain Grosjean, Artak Shahnas, Zhengbang Wang, Carlos Azucena, Matthew Addicoat, Thomas Heine, Joerg Lahann, Jörg Overhage, Stefan Bräse, Hartmut Gliemann, and Christof Wöll: Fabrication of Highly Uniform Gel Coatings by the Conversion of Surface-Anchored Metal−Organic Frameworks. JACS – Journal of the American Chemical Society. DOI:10.1021/ja409205s

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  • Britain to switch to paying in plastic – literally – with polymer banknotes

    Following a three-year research program and a public consultation, which took place in autumn 2013, the Bank of England has announced its decision to print its next £5 and £10 banknotes on polymer. According the Bank, polymer banknotes are resistant to dirt and moisture, making them cleaner and more durable than paper banknotes. As Bank of England Governor Mark Carney noted, "they last at least two and half times as long as paper banknotes, ensuring that the notes stay in circulation and that they remain of high quality. And because replacements are needed less often, they're both cheaper over time and more environmentally friendly." The new banknotes are emphatically being referred to as being made of "polymer" rather than "plastic," in connection with public perception. Chris Salmon, executive director for banking services and chief cashier said: "When the public had a chance to see the notes and feel them, they understood what they'd be like - and when they'd heard a description beforehand of plastic notes, they weren't quite sure what to expect. When you think plastic, you think of credit card, and actually, a polymer is very different to a credit card. So in terms of the public knowing what to expect, it helps." The response to the public consultation - in which nearly 13,000 people took part - proved to be overwhelmingly supportive of polymer notes. About 87 percent of those who responded were in favor of polymer, while only six percent were opposed and seven percent were neutral. The Bank also consulted with retailers, businesses and the cash industry. Carney: "After that public consultation, we're confident that the switch to polymer will have broad public support." A few people expressed concerns about how the new polymer notes felt, calling them more slippery to handle. The Bank concedes that polymer notes feel different from paper and can feel slippery when new, but says this declines over time once the notes are in circulation. The new notes will also have areas of raised print, which will give them a tactile quality and reduce the slippery feel. However, being thin and flexible, the new notes will still fit into wallets and purses as easily as the cotton-paper banknotes in use today. Bank of England aims to introduce the next £5 note (featuring Sir Winston Churchill) in 2016 and the £10 note (featuring Jane Austen) a year later. The new polymer notes will be slightly smaller - by around 15% - than their existing paper equivalents, but the current practice of note size increasing with note denomination will be maintained. Bank of England notes are currently large compared with their international counterparts, making the largest denomination notes harder to fit into cash handling technology and less convenient for everyday use. Smaller notes will also reduce printing and storage costs. The contract for printing the Bank of England's notes from April 2015 is currently being tendered. Notes will continue to be printed at the Bank's printing works in Debden, Essex. The Bank expects to enter a contract with Britain-based Innovia Security to supply the polymer material for the new-style £5 and £10 notes, in which case Innovia would establish a polymer production plant in Wigton, Cumbria, in 2016. The company is the producer of ClarityC, a high performance, biaxially oriented polypropylene film, ideally suited to banknote production, which is specially coated with an ink layer that enables it to carry the printed design features of banknotes. The material allows the inclusion of 'windows' or clear portions in the design, which enhance protection against counterfeits, as well as other security features not available to paper banknotes. However, the Bank stressed that the new polymer notes will retain the familiar look of Bank of England banknotes, including the portrait of the Queen, as well as depictions of historical characters of national significance. Polymer banknotes are by no means an exception, as countries increasingly discover their benefits. Over 25 countries currently issue polymer banknotes. These include Australia, which introduced them in 1988, New Zealand, Mexico, Singapore, Canada and most recently Fiji, and Mauritius, which both introduced polymer banknotes in 2013. Source: Plastics Today

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  • Investigated and copied: the secrets of spider silk unravelled

    Quelle: istockphoto Spiders are fascinating creatures. We find spider’s webs captivating because of their filigree structure. Although the individual threads are thinner than a human hair, they are more tear-resistant than steel, while being more elastic than rubber at the same time. These properties make them an ideal raw material for medical and technical applications. Attempts have been made for a long time to make industrial use of spider silk. The scientist Thomas Scheibel from the Faculty of Applied Natural Sciences at Bayreuth University has completed major work in this context, for which the DECHEMA Prize has now been awarded. Thomas Scheibel and his team have succeeded in synthesising and manufacturing spider silk on a large scale. The DECHEMA Prize committee at the Max Buchner Research Foundation came to the conclusion that it is now possible to develop new materials for technical and medical applications with it: e.g. for coatings, foams and gels or for nonwovens, fibres, yarns and films. The combination of properties is said to be unique: although the materials are very strong, they are also very elastic. This combination has not been possible up to now. There is tremendous potential for spider silk in biomedicine too. Thomas Scheibel has managed to produce capsules from spider silk proteins that for the first time carry out two functions at the same time: they protect enzymes against proteases and the disintegrating effect they have, while they at the same time enable the activity of the enclosed enzymes to be controlled and observed from the outside. One of the consequences of this is that completely new options are being opened up in the diagnostic field. Thomas Scheibel was born in 1969 and studied biochemistry at Regensburg University, where he obtained his doctorate in 1998. He then moved on to a post-doctoral position at Chicago University in the USA. In 2002, he took over the biomaterials chair at Munich Technical University, where he headed a study group and qualified as a professor. Since 2007, he has been a professor in the biomaterials faculty at Bayreuth University. Scheibel is the co-founder and partner of AMSilk GmbH that was spun off in 2008. He is a member of the editorial board of various magazines and of the advisory board of the biomimetics excellence network set up by the German state of Baden-Württemberg. Scheibel has received such awards as the Karl-Heinz Beckerts Prize (2008) and the Heinz Maier Leibnitz Medal (2007). Background information: the DECHEMA Prize has been awarded by the Max Buchner Research Foundation annually since 1951. It is presented for outstanding research work in the areas of technical chemistry, process engineering, biotechnology and chemical apparatus engineering. There is a special focus on work done by young research scientists. The work involved has to be of fundamental importance and demonstrate close integration of theoretical research and practical application. GD Source DECHEMA Gesellschaft für Chemische Technik und Biotechnologie e.V.

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  • Natural polymers: indentification of genuine amber

    Natural polymers: identification of genuine amber Determining the authenticity and origin of amber Very few people may suspect that amber is an extremely popular material in the jewellery, art and wellness fields. Special technology is needed to check the origin and authenticity of this natural polymer. Scientists from different disciplines are co-operating closely on this. Johannes Gutenberg-Universität, Mainz. Oluwadayo O. Sonibare and Thorsten Hoffmann from the Institute of Inorganic and Analytical Chemistry and Stephen F. Foley from the Geosciences and Earth System Research Department are looking for a way to determine the origin and authenticity of amber exactly. Amber – which is also known mineralogically as succinite – was originally a tree resin that escaped from pine trees or other conifers millions of years ago and solidified in contact with air. Large amounts of the dried resin made their way into the sea, sank into deep sediment layers, were covered by dust, sand and stones and were turned into amber in the course of time under high pressure in the absence of air. Most of the amber that is found can be dated back to the Tertiary, i.e. it is about 55 million years old, although there are some samples that do not go back this far. What all amber has in common is the fact that the same organic material is involved, which originally escaped from a host tree as resin and then solidified. Chemically speaking, amber is an inconsistent blend of substances that can be called polyester (more or less) and can be included in the terpene group. The origin of the name “Bernstein” (what amber is known as in German) The word “Bernstein” goes back to the Low German word “bernen”, which means “to burn”. And amber is in fact flammable, burning with a highly aromatic odour. Amber only dissolves to a limited extent in alcohol, ether, chloroform or turpentine oil. When it is ground, the material charges negatively and melts at 375°C. Due to its chemical and physical properties, it proves to be sensible to subject amber first of all to pyrolysis with subsequent gas chromatography of the pyrolysis fragments and their mass selective detection , in order to obtain information about its composition and thus its nature and origin. Pyrolysis Gas chromatography Mass selective detection Amber sometimes encloses and preserves the bodies of insects or plants that are millions of years old too. (Source: istockphoto) Incidentally: it took at least one million years before the material developed into what can be classified as amber. The Baltic amber found in the Baltic Sea is one of the very oldest amber materials. Amber is found in many different countries, such as England, Portugal, Spain or Italy as well as in Canada, Mexico, Japan, the Dominican Republic, Madagascar and Borneo. People find amber “fascinating because of its varying colours, its high light refraction and its golden yellow lustre after polishing. Amber feels sensual and warm and weighs surprisingly little. You want to touch it, wear it on your skin, hold it in your hand. It is still a popular pastime to collect amber on the Baltic Sea coast, because it is said to have healing, painkilling and soothing powers.” [3] Amber sometimes encloses and preserves the bodies of insects or plants that are millions of years old too. The recommendations made by the German Amber Museum – to identify materials in question by comparing their density in salt water [1] – may well be adequate to provide rough guidance in this context, but they are not good enough when a scientifically sound investigation is involved – and that is what the research scientists are interested in. Their objective is “to determine the molecular composition and chemotaxonomic aspects of Eocene amber from the Ameki Formation in Nigeria” [2]. With funding from the Alexander von Humboldt Foundation, Sonibare and colleagues are, among other things, using infrared spectroscopy (which has been described in sufficient detail in the literature about amber analysis) and gas chromatography with mass selective detection (GC/MS), in order to determine the molecular composition of different fossil plant resins. GERSTEL GmbH & Co. KG, Mülheim an der Ruhr. R&D Project Manager Dr Eike Kleine-Benne is sitting at a conference table talking to Oluwadayo O. Sonibare about the characteristics of amber as well as the problem faced when trying to pinpoint where genuine amber originally came from and to identify fake amber, in a nutshell: they are discussing the options available for analysing the composition and determining the specific properties of amber. A detailed examination of the sample material has proved to be sensible and right when choosing the appropriate analytical technology. Amber – which is also known mineralogically as succinite – was originally a tree resin that escaped from pine trees or other conifers millions of years ago and solidified in contact with air. (Source: istockphoto) Interesting chemical-analytical details Dr Oluwadayo O. Sonibare explains that the fossilisation of plant resin – which is what happens in the development of amber – is a complex maturing process that involves the loss of volatile components as well as the polymerisation and crosslinking of terpenoids and takes up to 100 million years to complete. He points out that amber is a complex blend of different terpenoids (mono-, sesqui, di- and triterpenoids), natural substances that are derived structurally from isoprene that is emitted by plants. In contrast to terpenes, terpenoids contain functional groups. The scientist emphasises that knowledge about the chemical composition of amber is useful in order – on the one hand – to enable authentic amber to be distinguished from imitations and – on the other hand – to make it possible to determine its origin or carry out more extensive studies. Important analytical methods for the characterisation of amber are infrared spectroscopy (IR), Raman spectroscopy and GC/MS analysis of amber extracts and/or pyrolysis of the amber itself with subsequent GC/MS analysis. Dr Eike Kleine-Brenne reports that infrared spectroscopy (IR) is used, for example, to distinguish Baltic Sea amber from other amber that is found. The main distinguishing feature here is apparently an unmistakable section in the IR spectrogram known as the Baltic shoulder at 1,250 to 1,175 cm–1; Dr Kleine-Benne explains that it is associated with succinic acid that is present in Baltic Sea amber. According to Dr Eike Kleine-Benne, the limitations of the IR method are quickly reached when differentiation according to the nature and origin of the amber is required, however, because most types of amber have similar patterns in the IR spectrum, which makes it more difficult to identify individual features. Raman spectra, on the one hand, are, useful to identify differences in the maturing process of amber but not to determine its geographical origin. GC/MS only makes it possible, on the other hand, to determine the molecular structure of soluble components, although they rarely account for more than 20 per cent of the total resin. The solution is a combination of different approaches Pyrolysis GC/MS is different; as Dr Eike Kleine-Benne explains, this enables the user to separate the polymer components, i.e. the non-soluble and non-volatile macromolecules of the amber, into individual components and to identify them clearly in the mass spectrum according to their molecular structure. Interesting technical details for material scientists and laboratory users: Data collection with pyrolysis GC/MS People find amber fascinating because of its varying colours, its high light refraction and its golden yellow lustre after polishing. Amber feels sensual and warm and weighs surprisingly little. You want to touch it, wear it on your skin, hold it in your hand. It is still a popular pastime to collect amber on the Baltic Sea coast, because it is said to have healing, painkilling and soothing powers. (Source: istockphoto) What remains to be said by way of conclusion Dr Oluwadayo O. Sonibare reports that a previous study provided the first information available about the molecular composition of fossil resins from the Eocene Ameki Formation in Nigeria. Pyrolysis GC/MS analyses made it clear that the amber belongs to Class 1B, which is derived from standard labdatrien structures that lack succinic acid. The pyrolysis products of the amber were dominated by labdane-like diterpenoids and some sesquiterpenoids. The fact that only labdane diterpenoids were present in and plant triterpenoids were absent from the amber suggests that this resin came from a conifer (gymnosperm). As a result, Dr Oluwadayo O. Sonibare, Professor Thorsten Hoffmann and Professor Stephen F. Foley from Johannes Gutenberg University in Mainz now have an instrument that helps them to determine the origin of amber, in addition to obtaining extensive information for their amber research: Dr Eike Kleine-Benne reports that the second scientific publication is set to appear in a recognised journal in the near future. Source [1] www.deutsches-bernsteinmuseum.de [2] O. O. Sonibare T. Hoffmann, S. F. Foley: Molecular composition and chemotaxonomic aspects of Eocene amber from the Ameki Formation, Nigeria, Organic Geochemistry 51 (2012) 55–62 [3] www.planet-wissen.de/natur_technik/schmuck/faszination_bernstein Further information in the Internet Amber (known in German as “Bernstein”, from the Middle Low German word “Börnsteen” = “Brennstein”) is the word used for the clear to opaque yellow gemstone consisting of fossil resin that has been known for thousands of years and is particularly common in the Baltic Sea area. … -> For more information, go to en.wikipedia.org/wiki/Amber Author Guido Deußing

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  • Interesting technical details for material scientists and laboratory users

    Interesting technical details for material scientists and laboratory users Data collection with pyrolysis GC/MS For the purposes of the investigation, Eocene amber samples (note: Eocene is the name given to a period in the earth’s history that began about 56 million years ago and ended about 34 million years ago) from the Ameki Formation in Nigeria were used that were made available by the Hunterian Museum at Glasgow University. The sample material was ground up and pyrolysed in portions of 200 µg at 480°C for 20 seconds. The following equipment combination was used for the pyrolysis GC/MS: Agilent GC 6890N with the GERSTEL Cooled Injection System (CIS), the GERSTEL Thermal Desorption Unit (TDU), the GERSTEL Multi Purpose Sampler (MPS) and the Agilent MS 5795B Inert XL (Triple Axis). The pyrolysis operation itself was carried out using the GERSTEL Pyro, a special pyrolysis module, by which the GERSTEL TDU can be extended quickly without any major modifications. Further details of technical relevance: the TDU was operated in split mode, in order to remove surplus solvent. The Cooled Injection System (CIS) was set at a temperature of 300°C and used as a hot split interface. The GC was operated in split mode (1:20) and was equipped with a ZB-5MS quartz glass column (30 m x 0.25 µ x 0.25 mm, Phenomenex). The temperature program of the GC oven was as follows: 60°C (2 min.) – 6°C/min. – 300°C (10 min.). Helium was used as the carrier gas with a constant flow of 1 ml/min. The mass spectrometer was operated in Electron Impact (EI) ionisation mode, with the ionisation energy set at 70 eV and the source and quadrupole temperatures set at 230°C and 150°C respectively. Full-scan mass spectra were recorded over a mass range of 50 to 650 Da. ChemStation software was used to collect and process the data. Individual compounds were identified by comparing the mass spectra with MS library data and information from the literature. Hunterian Museum Step by step to in-depth information Zunächst erfolgte die reine Pyrolyse des gemahlenen Bernsteins. Im Pure pyrolysis of the ground amber was carried out first of all. A number of the components described in the literature were identified in the chromatogram, such as a series of fatty acids (FA), i.e. norchrysanthemum acid (FA I), naphthalene-1-carboxylic acid-1,2,3,4,4a,7,8,8a-octahydro-1,4a,6-trimethyl (FA II), naphthalene-1-carboxylic acid-1,2,3,4,4a,7,8,8a-octahydro-1,4a,5,6-tetramethyl (FA III) and naphthalene-1-carboxylic acid-1,2,3,4,4a,5,8,8a-octahydro-1,4a,6-trimethyl-5-methylene (FA V). In order to obtain more in-depth information, the amber samples were derivatised (methylised) in situ, i.e. during the 20-second pyrolysis operation, after the pyrolysis GC/MS process using tetramethylammonium hydroxide (TMAH); this process is also known as thermochemolysis. The fatty acids were converted into their corresponding fatty acid methyl esters (FAMES) in this context: norchrysanthemum acid methyl ester (FAME I), naphthalene-1-carboxylic acid-1,2,3,4,4a,7,8,8a-octahydro-1,4a,6-trimethyl methyl ester (FAME II), naphthalene-1-carboxylic acid-1,2,3,4,4a,7,8,8a-octahydro-1,4a,5,6-tetramethyl methyl ester (FAME III), methyl-1,2,3,4-tetrahydro-1,5,6-trimethyl-1-naphthalene carboxylate (FAME IV), naphthalene-1-carboxylic acid-1,2,3,4,4a,5,8,8a-octahydro-1,4a,6-trimethyl-5-methylene methyl ester (FAME V) and methyl-16,17-dinorcallitrisate (FAME VI). Dr Eike Kleine-Benne explains the difference between pure pyrolysis and the thermochemolysis process as follows: “In the pyrolysis chromatogram, the peaks of FA (I), FA (II), FA (III) and FA (V) are wide and in some cases have a sawtooth shape, a typical phenomenon for polar compounds like fatty acids that are separated on a non-polar column. In contrast to this, the corresponding methylised compounds FAME (I), FAME (II), FAME (III) and FAME (V) elute in the thermochemolysis chromatogram as well-defined sharp peaks. It was only possible to identify FAME (IV) and FAME (V) in the thermochemolysis chromatogram. It is very clear that pyrolysis with TMAH generates more detailed information about the sample.”

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  • Polymer-Innovation: Energiespeicher aus Faserverbundstoffen

    Electron microscopic picture of the single fibre pull-out Most batteries are bulky and heavy. So why not use an existing case such as, for example, the car body as energy storage? European researchers came up with this idea and organised the StorAGE EU project to develop flexible power storage from fibre composites. The project has now been completed after three and a half years and now provides the first results. The carmaker Volvo has equipped a test vehicle with the new composite material which is placed in the engine bonnet and boot lid and provides an extended car battery. The BAM Federal Institute for Materials Research and Testing was involved in the project which was headed by the Imperial College London with nine research institutes and industrial partners also participating. BAM carried out the mechanical tests on the energy storage devices and participated in the development of a conductive epoxy resin for fibre-reinforced composites. So how does the new energy storage operate? There are supercapacitors in the engine bonnet or boot lid made of carbon fibres. Supercapacitors are a further development of conventional capacitors, which for example have been used in photo flash equipment for some time. They are very quick to recharge, are durable and are capable of working at minus 40 degrees Celsius. The carbon fibre and CNT composite is enclosed by a polymer resin. Glass fibre mats are used as an insulation layer between the energy-storing layers. BAM coordinated various investigations on self-discharge, electrolyte decomposition and material stability. The single fibre “pull-out test" developed at BAM was used to determine the adhesion of individual fibres to the surrounding material. Fibre composites contain many fibre bundles, each comprising several thousand individual fibres. To produce stable materials from this tissue, they are impregnated with a curable plastic, for example, epoxy resin. The fibres studied in the single fibre pull-out test may be very thin. For instance, a carbon fibre is only about five microns thick, or about 20 times thinner than a human hair and almost invisible to the naked eye. The fibre is embedded in a polymer matrix droplet and fixed by an adhesive on the other side. An optical microscope allows the tracking of a crack process during measurement. The magnitude of force transmitted between the plastic and the fibre is then a measure of the coupling strength. For the project, it was important to ensure that the novel conductive resin systems have good adhesion to the fibres – thus the composite is stable enough to be installed in an automobile. "In general, the energy storage works," says Gerhard Kalinka, a BAM engineer. It is promising, but one is still at the beginning of the development because not all questions have been completely clarified. For example, how safe is the system when it comes to damage? In the Volvo prototype, the car battery can be replaced to some extent, however research is still needed until a genuine electric car can be supplied with energy in this way. Nevertheless, Kalinka sees promising applications for computers and mobile phones as well. There, the traditional battery may disappear and the housing can deliver the necessary power over the long term. In addition to weight saving, a further advantage of super capacitors would be a fast recharge within minutes. GD Source Federal Institute for Materials Research and Testing (BAM)

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  • Plastic: inspiration for space research scientists

    Space with its endless expanses is an inspiration not just for the creators of science fiction literature, Hollywood films or TV series. Space is a challenge to the scientific community too – and one that can only be tackled with the help of different materials. Plastic is one of them ... Materials for space stations or satellites are put into orbit by rockets at present. “But this is not just expensive; it consumes valuable raw materials too”, says Professor Dr Klaus D. Jandt from Friedrich Schiller University in Jena. “Because rockets can only be used for transport purposes once. This explains why an intensive search is currently being made for alternative ways to put things into orbit”, says the Material Science Professor. Jandt and his colleagues have high hopes for the concept of a space lift, in which a “cabin” travels from the surface of the earth to a geostationary space station and releases satellites directly there. The material scientists from Jena have now succeeded in making major progress in development of the basis for this: as the physicist Matthias Arras, Professor Jandt and their colleagues from Jena University report in the current issue of the well-known American journal “Carbon”, they have developed a new polymer-ceramic composite that has the potential to be used later on in a space lift. Carbon nanotubes (CNT) are the basis for the innovative new material. “These cigar-shaped tubes made of pure carbon have up to 30 times higher tensile strength than steel and are substantially lighter as well”, explains Jandt. He explains that this makes them a particularly attractive proposition for use as a “lift cable” into orbit, which would need not only to have extremely high tensile strength but also be very light. “Such a cable could not be made from any other material that has been known up to now”, says Jandt. However, the CNTs can only realise their full potential when they are all aligned in the same direction, “somewhat like cigars in a box”, says Professor Jandt and continues: “Aligning the CNTs, which have a diameter of only a few billionths of a metre, is still causing problems.” And this is exactly where the research scientists from Jena have now achieved a breakthrough. They first of all incorporated the CNTs in a polymer melt, which was then stretched (pulled) extensively. “Stretching the plastic melt creates a highly aligned polymer substrate”, explains Matthias Arras, a doctoral student in Professor Jandt’s team. This means that the polymer substrate already has very high tensile strength in itself. When the polymer melt solidifies, some of the polymer takes on an amorphous form and interface crystallisation occurs. During the stretching process, crystals grow on the carbon nanotubes in an orderly pattern and bond with them. “In the course of the stretching process, the polymer chains of the amorphous part of the polymer lock with the crystals on the carbon nanotubes and as a result pull all of them in the same direction”, explains Arras. “The result is extremely high alignment of the nanotubes, something that has not be observed in polymers in this form up to now.” Source: Arras MML et al. Alignment of multi-wall carbon nanotubes by disentanglement in ultra-thin melt-drawn polymer films. Carbon (2013), http://dx.doi.org/10.1016/j.carbon.2013.04.049

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